Special Oil & Gas Reservoirs ›› 2023, Vol. 30 ›› Issue (3): 155-160.DOI: 10.3969/j.issn.1006-6535.2023.03.020

• Drilling & Production Engineering • Previous Articles     Next Articles

Development of Selective Water Plugging Interfacial Gel

Li Jun1,2, Wang Li2,3, Li Yong1, Chen Qilong1, Wang Sha1, Lu Hongsheng2,3   

  1. 1. Sinopec Northwest Oilfield Company, Urumqi, Xinjiang 842012, China;
    2. Southwest Petroleum University, Chengdu, Sichuan 610500, China;
    3. Oil & Gas Field Applied Chemistry Key Laboratory of Sichuan Province, Chengdu, Sichuan 610500, China
  • Received:2022-12-29 Revised:2023-03-10 Online:2023-06-25 Published:2023-07-13

Abstract: In response to the disadvantages of poor oil-water selectivity and high injection pressure of high polymer selective water plugging gels, small-molecule gel factors were synthesized through the acid-amine neutralization reaction between N,N-dimethylcyclohexylamine and stearic acid, arachidic acid and behenic acid respectively, which can spontaneously form interfacial gels at the oil-water interface. The microscopic appearance and rheological properties of the interfacial gels were investigated by polarizing microscope and rheometer, and the selective water plugging performance of the small-molecule gel factor at the oil-water interface was investigated by displacement experiments. The results show that the viscosity of the interfacial gel formed by the small-molecule gel factor at the oil-water interface can reach 105 mPa·s or more, and the yield stress is as high as 100 Pa; the displacement experiment proves that the small-molecule gel factor can selectively block the water channel, the breakthrough pressure gradient is up to 2.74 MPa/m, and the recovery rate is enhanced by 21.3 percentage points. The small-molecule gel factor has good oil-water selectivity and can effectively enhance the recovery of crude oil, so it is worth to be promoted and applied.

Key words: selective water plugging, small-molecule gel factor, interfacial gel, fatty acid

CLC Number: