Geologic Exploration

Pore Structure Characterization and Micro-Heterogeneity of Carboniferous-Permian Organic-Rich Shalein Julu

  • Yao Shuanghong ,
  • Li Xueyuan ,
  • Li Peng ,
  • Wang Huijun ,
  • Chen Shangbin
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  • 1. China University of Mining & Technology, Xuzhou, Jiangsu 221116, China;
    2. MOE Key Laboratory of Coal-bed Methane Resources and Accumulation Process, China University of Mining and Technology,Xuzhou,Jiangsu 221116,China;
    3. Hebei Coalfield Geological Survey Institute, Xingtai 054000, Hebei, China

Received date: 2020-02-06

  Revised date: 2020-05-10

  Online published: 2022-02-18

Abstract

In order to reveal the fractal performance and micro heterogeneity of riched organic in shale pores, X-ray diffraction, scanning electron microscopy and low temperature liquid nitrogen adsorption were used to qualitatively and quantitatively characterize the pore structure of riched organic in shale in Julu. The FHH model was used to calculate the fractal dimension of pores and discuss the influencing factors of micro heterogeneity. Research indicates that the shale mainly composed by clay minerals and quartz. The corresponding clay minerals are dominated by illite-smectite mixed layer, illite and chlorite. The pores mainly consist of organic pore, intergranular pore and micro fracture. The micro heterogeneity shows a difference for different pore size intervals, and there is a stronger micro heterogeneity in the range of 4.34~100.00 nm. The fractal dimension is positively and negatively related to clay minerals and brittle minerals respectively. The pore micro heterogeneity is also dependent on the structure and diagenesis. This research could provide certain theoretical reference for the shale gas exploration in Julu.

Cite this article

Yao Shuanghong , Li Xueyuan , Li Peng , Wang Huijun , Chen Shangbin . Pore Structure Characterization and Micro-Heterogeneity of Carboniferous-Permian Organic-Rich Shalein Julu[J]. Special Oil & Gas Reservoirs, 2020 , 27(4) : 41 -48 . DOI: 10.3969/j.issn.1006-6535.2020.04.006

References

[1] 赵文智,董大忠,李建忠,等.中国页岩气资源潜力及其在天然气未来发展中的地位[J].中国工程科学,2012,14(7):46-52.
ZHAO Wenzhi,DONG Dazhong,LI Jianzhong,et al.The resource potential and future status in natural gas development of shale gas in China[J].China Engineering Science,2012,14(7):46-52.
[2] 邹才能,赵群,董大忠,等.页岩气基本特征、主要挑战与未来前景[J].天然气地球科学,2017,28(12):1781-1796.
ZOU Caineng,ZHAO Qun,DONG Dazhong,et al.Geological characteristics,main challenges and future prospect of shale gas[J].Natural Gas Geosciences,2017,28(12):1781-1796.
[3] 董大忠,邹才能,李建忠,等.页岩气资源潜力与勘探开发前景[J].地质通报,2011,30(2):324-336.
DONG Dazhong,ZOU Caineng,LI Jianzhong,et al.Resourcepotential,exploration and development prospect of shale gas in the whole world[J].Geological Bulletin of China,2011,30(2):324-336.
[4] 王世谦.页岩气资源开采现状、问题与前景[J].天然气工业,2017,37(6):115-130.
WANG Shiqian.Shale gas exploitation: status, issues and prospects[J].Natural Gas Industry,2017,37(6):115-130.
[5] 郑民,李建忠,吴晓智,等.我国常规与非常规天然气资源潜力、重点领域与勘探方向[J].天然气地球科学,2018,29(10):1383-1397.
ZHENG Min,LI Jianzhong,WU Xiaozhi,et al.China's conventional and unconventional natural gas resource potential, key exploration fields and direction[J].Natural Gas Geoscience,2008,29(10):1383-1397.
[6] 刘娟,赵伟,赵鲁阳.河北平原地区石炭—二叠系页岩气烃源岩分布规律研究[J].中国煤炭地质,2018,30(增刊2):28-31.
LIU Juan,ZHAO Wei,ZHAO Luyang.Study on Permo-Carboniferous shale gas source rock distribution pattern in Hebei Plain Area[J].China Coal Geology,2008,30(S2):28-31.
[7] 张新生,于海成,张华.河北省页岩分布及页岩气前景[J].中国煤炭地质,2019,31(1):59-65.
ZHANG Xinsheng,YU Haicheng,ZHANG Hua.Shale distribution in Hebei Province and shale gas prospect[J].China Coal Geology,2019,31(1):59-65.
[8] 房涛,张立宽,刘乃贵,等.核磁共振技术定量表征致密砂岩气储层孔隙结构——以临清坳陷东部石炭系—二叠系致密砂岩储层为例[J].石油学报,2017,38(8):902-915.
FANG Tao,ZHANG Likuan,LIU Naigui,et al.Quantitative characterization of pore structure of tight gas sandstone reservoirs by NMR T2 spectrum technology:a case study of Carboniferous-Permian tight sandstone reservoir in Linqing Depression[J].Acta Petrolei Sinica,2007,38(8):902-915.
[9] 孙耀庭,徐守余,张世奇,等.渤海湾盆地临清坳陷西部中生界烃源岩生烃演化[J].天然气地球科学,2015,26(10):1910-1916.
SUN Yaoting,XU Shouyu,ZHANG Shiqi,et al.Evolution of the Mesozoic source rocks in the west Linqing Depression[J].Natural Gas Geoscience,2015,26(10):1910-1916.
[10] 陈武珍,陈红汉,李文涛,等.临清坳陷东部石炭系—二叠系二次生烃差异性研究[J].沉积学报,2012,30(1):179-188.
CHEN Wuzhen,CHEN Honghan,LI Wentao,et al.Study on differentiation of secondary hydrocarbon generation for the Carboniferous-Permian source rocks in the eastern Linqing Depression[J].Acta Sedimentologica Sinica,2012,30(1):179-188.
[11] 王金旗.南阳凹陷东部复杂断裂带油气勘探目标分析[J].石油地质与工程,2018,32(1):14-18.
WANG Jinqi.Hydrocarbon exploration target analysis of the complex fault zone in the eastern Nanyang Sag[J].Petroleum Geology & Engineering,2018,32(1):14-18.
[12] 郭华,夏斌,陈根文,等.临清坳陷中新世玄武岩地球化学特征及大地构造意义[J].石油学报,2005,26(4):5-11.
GUO Hua,XIA Bin,CHEN Genwen,et al.Geochemical and geotectonic features of Miocene basalts in Linqing Sag[J].Acta Petrolei Sinica,2005,26 (4):5-11.
[13] 徐飞,邓小利,王卫东.邯郸煤田晚古生代煤系层序地层及岩相古地理研究[J].中国煤炭地质,2018,30(增刊2):9-12,40.
XU Fei,DENG Xiaoli,WANG Weidong. Study on Late Paleozoic coal measures sequence stratigraphy and lithofacies paleogeography in Handan Coalfield[J].Coal Geology of China,2008,30(S2):9-12,40.
[14] 洪铭.临清坳陷石炭—二叠纪地层特征与分布[D].青岛:山东科技大学,2007.
HONG Ming.Characteristics and distribution of Carboniferous-Permian strata in Linqing Depression [D].Qingdao:Shandong University of Science and Technology,2007.
[15] 赵洪刚,梁吉坡,陈晓燕.临清坳陷晚古生代沉积环境及演化分析[J].山东国土资源,2012,28(3):1-4.
ZHAO Honggang,LIANG Jipo,CHEN Xiaoyan.Analysis of sedimentary environment and evolution in Late Paleozoic era in Linqing Depression [J].Shandong Land and Resources,2012,28(3):1-4.
[16] 张鹏飞,陈世悦,张关龙.临清探区石炭—二叠系沉积演化特征[J].中国矿业大学学报,2008,37(2):270-275.
ZHANG Pengfei,CHEN Shiyue,ZHANG Guanlong.Characteristics of sedimentary evolution of the Permo-Carboniferous system in Linqing prospect area[J].Journal of China University of Mining and Technology,2008,37(2):270-275.
[17] 何彦庆,郑丽,闫长辉,等.页岩储层标准等温吸附曲线的建立——以鄂尔多斯盆地长7页岩储层为例[J].岩性油气藏,2018,30(3):92-99.
HE Yanqing,ZHENG Li,YAN Changhui,et al.Establishment of standard adsorption isotherms for shale reservoirs:a case of Chang7 shale reservoir in Ordos Basin[J].Lithologic Reservoirs,2018,30(3):92-99
[18] Zhang Q,Liu R,Pang Z,et al.Characterization of microscopic pore structures in Lower Silurian black shale(S1l),southeastern Chongqing,China[J].Marine and Petroleum Geology,2016,71:250-259.
[19] 陈尚斌,朱炎铭,王红岩,等.川南龙马溪组页岩气储层纳米孔隙结构特征及其成藏意义[J].煤炭学报,2012,37(3):438-444.
CHEN Shangbin,ZHU Yanming,WANG Hongyan,et al.Structure characteristics and accumulation significance of nanopores in Longmaxi shale gas reservoir in the southern Sichuan Basin[J].Journal of China Coal Society,2012,37(3):438-444.
[20] 陈燕燕,邹才能,MARIA Mastalerz,等.页岩微观孔隙演化及分形特征研究[J].天然气地球科学,2015,26(9):1646-1656.
CHEN Yanyan,ZOU Caineng,MARIA Mastalerz,et al.Porosity and fractal characteristics of shale across a maturation gradient[J].Natural Gas Geosciences,2015,26(9):1646-1656.
[21] 宋晓夏,唐跃刚,李伟,等.中梁山南矿构造煤吸附孔分形特征[J].煤炭学报,2013,38(1):134-139.
SONG Xiaoxia,TANG Yuegang,LI Wei,et al.Fractal characteristics of adsorption pores of the tectonic coal from Zhongliangshan southern coalmine[J]. Journal of China Coal Society,2013,38(1):134-139.
[22] PFEIFERPER P,AVNIR D.Chemistrynonintegral dimensions between two and three[J].The Journal of Chemical Physics,1983,79(7):3369-3558.
[23] 张岩,刘金城,徐浩,等.陆相与过渡相煤系页岩孔隙结构及分形特征对比——以鄂尔多斯盆地东北缘延安组与太原组为例[J].石油学报,2017,38(9):1036-1046.
ZHANG Yan,LIU Jincheng,XU Hao,et al.Comparison between pore structure and fractal characteristics of continental and transitional coal measures shale: a case study of Yan'an and Taiyuan Formations at the northeastern margin of Ordos Basin[J].Acta Petrolei Sinica,2017,38(9):1036-1046.
[24] 戴方尧,胡海燕,张爱华.有机质页岩孔隙分形模型的适用性研究[J].煤炭科学技术,2019,47(2):168-175.
DAI Fangyao,HU Haiyan,ZHANG Aihua.Suitability study on fractal model of organic shale pore[J].Coal Science and Technology,2019,47(2):168-175.
[25] 杨宇,孙晗森,彭小东,等.煤层气储层孔隙结构分形特征定量研究[J].特种油气藏,2013,20(1):31-33,88.
YANG Yu,SUN Hansen,PENG Xiaodong,et al.Quantitative study on fractal characteristics of the structure of CBM reservoir[J].Special Oil & Gas Reservoirs,2013,20(1):31-33,88.
[26] 李菊花,郑斌.微观孔隙分形表征新方法及其在页岩储层中的应用[J].天然气工业,2015,35(5):52- 59.
LI Juhua,ZHENG Bin.A new method for fractal characterization of microscopic pores and its application in shale reservoirs[J].Natural Gas Industry,2015,35(5):52-59.
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