Reservoir Engineering

Experiment on Enhanced Oil Recovery by In-situ Catalytic Reforming of Super-heavy Oil

  • Tang Xiaodong ,
  • Chen Tingbing ,
  • Guo Erpeng ,
  • Guan Wenlong ,
  • Jiang Youwei ,
  • Li Jingjing
Expand
  • 1. Southwest Petroleum University, Chengdu, Sichuan 610500, China;
    2. Research Institute of Petroleum Exploration & Development, Beijing 100083, China

Received date: 2021-05-31

  Revised date: 2021-11-15

  Online published: 2023-01-10

Abstract

In order to solve the problems of high flow resistance and difficulties in production of super-heavy oil in low-permeability area during steam stimulation and steam flooding, in-situ catalytic reforming and viscosity reduction technology for super-heavy oil in low-permeability area was proposed. Reactor method and physical model experiment method were used to select high-efficiency in-situ reforming catalysts, and the catalyst injection method was studied. Five types of catalysts and their reforming conditions were selected. The study showed that: when organozinc was used as catalyst, the amount of catalyst was 0.1%, the water content of heavy oil was 50%, the super-heavy oil showed a better performance in reforming and viscosity reduction; the effect of physical model experiment method on in-situ catalytic reforming and viscosity reduction was better than that of reactor method; under conditions that the water content of heavy oil was 50%, the amount of catalyst was 0.1%, the reaction temperature was 240 ℃, the back pressure of sand filling pipe was 8 to 10 MPa and the reaction time was 24 h, the viscosity of heavy oil was decreased to 54 260 mPa·s from 145 000 mPa·s, and the viscosity reduction rate was 62.58%; the density and acid value of the heavy oil reformed by physical model experiment were decreased, the content of heavy components (colloid and asphaltene) was decreased by 10.85 %, and the fractions before 300 ℃ and 500 ℃ were increased by 6.75% and 17.29%, respectively. At 240℃ and 10 MPa, the self-made biomass-based profile control agent was used to block the dominant seepage channel, and the catalyst was injected into the low-permeability sand-packed pipe and then water flooded. The viscosity of the reformed heavy oil was reduced to 68 450 mPa·s, the viscosity reduction rate was 52.79%, the process flow resistance was reduced by 19.74%, the recovery rate reached 95.22%, and the comprehensive recovery rate of heavy oil was increased from 46.94% to 85.13%. The method provides references for in-situ catalytic reforming and viscosity reduction of heavy oil in low-permeability areas to enhance the oil recovery in the process of steam stimulation and steam flooding of super-heavy oil.

Cite this article

Tang Xiaodong , Chen Tingbing , Guo Erpeng , Guan Wenlong , Jiang Youwei , Li Jingjing . Experiment on Enhanced Oil Recovery by In-situ Catalytic Reforming of Super-heavy Oil[J]. Special Oil & Gas Reservoirs, 2022 , 29(1) : 114 -120 . DOI: 10.3969/j.issn.1006-6535.2022.01.017

References

[1] 郑伟, 袁忠超, 田冀, 等.渤海稠油不同吞吐方式效果对比及优选[J].特种油气藏,2014, 21(3):79-82,154.
ZHENG Wei,YUAN Zhongchao,TIAN Ji,et al.Comparison and selection of different steam stimulation modes for Bohai heavy oil[J].Special Oil & Gas Reservoirs,2014,21(3):79-82,154.
[2] 关文龙, 席长丰, 陈亚平,等.稠油油藏注蒸汽开发后期转火驱技术[J].石油勘探与开发,2011, 38(4):452-462.
GUAN Wenlong,XI Changfeng,CHEN Yaping,et al.Fire-flooding technologies in post-steam-injected heavy oil reservoirs[J].Petroleum Exploration and Development,2011,38(4):452-462.
[3] 吴婷婷,廖辉,葛涛涛,等.渤海特稠油油藏油溶性降黏体系辅助热采室内实验研究[J].当代化工,2020,49(8):1618-1621,1625.
WU Tingting,LIAO Hui,GE Taotao,et al.Laboratory experimental study on thermal recovery assisted by oil soluble viscosity reduction system in Bohai extra heavy oil reservoir[J].Contemporary Chemical Industry,2020,49(8):1618-1621,1625.
[4] 陈尔跃,刘永建,梁敏,等.油溶性油酸镍对辽河稠油的降黏作用[J].大庆石油学院学报,2010, 34(6):68-71,122.
CHEN Eryue,LIU Yongjian,LIANG Min,et al.A study on the viscosity reduction of Liaohe heavy oil by oil-soluble nickel oleate[J].Journal of Daqing Petroleum Institute,2010,34(6):68-71,122.
[5] 李航,孟江,王梦雨,等.NiFe2O4催化剂的制备及稠油降黏性能的研究[J].云南化工,2021,48(2):55-56.
LI Hang,MENG Jiang,WANG Mengyu,et al.Preparation of NiFe2O4 catalyst and study on viscosity reduction of heavy oil[J].Yunnan Chemical Technology,2021,48(2):55-56.
[6] SUWAID M A,VARFOLOMEEV M A,Al-MUNTASER A A,et al.In-situ catalytic upgrading of heavy oil using oil-soluble transition metal-based catalysts[J].Fuel,2020,281(1):118753.
[7] YUAN C,EMELIANOV D A,VARFOLOMEEV M A,et al.Mechanistic and kinetic insight into catalytic oxidation process of heavy oil in in-situ combustion process using copper(Ⅱ)stearate as oil soluble catalyst[J].Fuel,2021,284(15):118981.
[8] 黄佳,江航,赵长虹,等.复配纳米催化剂在稠油降黏中的应用及其机理[J].中国粉体技术,2020,26(1):68-74.
HUANG Jia,JIANG Hang,ZHAO Changhong,et al.Effects and mechanism of combined nano-catalysts on viscosity reduction of heavy oil[J].China Powder Science and Technology,2020,26(1):68-74.
[9] LI J,ZHANG Z,QIN G F,et al.Fe/HZSM-5 catalytic pyrolysis cellulose as hydrogen donor for the upgrading of heavy crude oil by one-pot process[J].Fuel,2021,298(15):120880.
[10] 景萍,李清彪,韩梅,等.Ni2+和Sn2+改性的SO42-/ZrO2固体超强酸催化剂对稠油的降黏性能[J].石油化工,2007,36(3):237-241.
JING Ping,LI Qingbiao,HAN Mei,et al.Effect of Ni2+ and Sn2+ Modified SO42-/ZrO2 solid super-acid catalysts on visbreaking of heavy petroleum oil[J].Petrochemical Technology,2007,36(3):237-241.
[11] LI J J,CHEN X D,TANG X D,et al.Upgrading heavy and extra-heavy crude oil for transportation by use an iron oil-soluble catalyst[J].Petroleum Science and Technology, 2017,35(12):1203-1208.
[12] LI J J,ZHOU T D,TANG X D,et al.Viscosity reduction process of heavy oil by catalytic co-pyrolysis with sawdust[J].Journal of Analytical and Applied Pyrolysis,2019,140(4):444-451.
[13] 王嵩, 王伟, 肖庆华,等.分子膜提高采收率机理及驱油效率分析[J].应用化工,2015,44(增刊1): 88-92.
WANG Song,WANG Wei,XIAO Qinghua,et al.Mechanism of enhanced oil recovery by molecular film and analysis of oil displacement efficiency[J].Applied Chemical Industry,2015,44(S1):88-92.
[14] CLARK P D,HYNE J B.Chemistry of organosulphur compound types occurring in heavy oil sands:3.reaction of thiophene and terahydrothiophene with vanadyl and nickel salts[J].Fuel,1984,62(8):1649 -1654.
[15] 陈尔跃,刘永建,闻守斌. 辽河稠油中胶质在催化水热裂解反应中的降解[J]. 石油与天然气化工,2006,35(1):49-50.
CHEN Eryue,LIU Yongjian,WEN Shoubin.A study on the degradation of the resin in Liaohe heavy oil during catalytic aquathermolysis reaction[J].Chemical Engineering of Oil and Gas,2006,35(1):49-50.
Outlines

/