Reservoir Engineering

Experimental Study on Development Mechanism and Production Characteristics of CO2-Pure Water Stimulation of Inter-Salt Shale Oil

  • Zhang Chong ,
  • Xiao Hanmin ,
  • Xiao Pufu ,
  • Cui Maolei ,
  • Zhao Qingmin ,
  • Zhao Ruiming
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  • 1. Northeast Oil & Gas Branch of SINOPEC, Changchun, Jilin 130072, China;
    2. Research Institute of Petroleum Exploration & Development, Beijing 100083, China;
    3. Centre of SINOPEC Petroleum Exploration and Production Research Institute, Beijing 100083, China;
    4. State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development, Beijing 100083, China;
    5. SINOPEC Northwest Oil Field Company, Urumqi, Xinjiang 830011, China

Received date: 2021-01-18

  Revised date: 2021-11-18

  Online published: 2023-01-10

Abstract

The shale oil reservoirs in Qianjiang Sag are of abundant reserves, and their pores are rich in a variety of soluble minerals. In the development with CO2 - pure water stimulation, the supercritical characteristics of CO2 can be utilized for oil displacement and the CO2 sequestration in the target reservoirs also can be improved, which effectively reduce CO2 emissions. However, the key to implementation of this method lies in whether the CO2- pure water system can enter the shale micro-nano pores and effectively drive the crude oil in the pores. Experiments of stimulation with CO2, CO2- pure water and CO2- formation water were designed, the stimulation characteristics of CO2 injection, CO2- pure water injection and CO2- formation water injection were clarified based on NMR method, and the law and mechanism of crude oil production in different pores were summarized. The experimental results showed that the stimulation efficiency of CO2- pure water injection was 8.62 percentage points higher than that of CO2 injection, and 12.66 percentage points higher than that of CO2- formation water injection, and the acidic fluid formed by the combination of CO2- pure water could dissolve the soluble minerals on the pore surface, improve the pore connectivity and enhance the reservoir permeability, and effectively increase the production of crude oil in pores smaller than 0.01 μm and 0.01 to 0.10 μm. After multiple cycles of stimulation, the volumetric solubility of ionic substances in the produced liquid was decreased significantly, indicating that the subsequent injection of pure water failed to expand the swept volume, but only improved the production of crude oil. This study proves that the CO2- pure water injection can effectively improve the recovery rate of shale reservoirs, and provides a new idea for the effective development of onshore shale oil.

Cite this article

Zhang Chong , Xiao Hanmin , Xiao Pufu , Cui Maolei , Zhao Qingmin , Zhao Ruiming . Experimental Study on Development Mechanism and Production Characteristics of CO2-Pure Water Stimulation of Inter-Salt Shale Oil[J]. Special Oil & Gas Reservoirs, 2022 , 29(1) : 121 -127 . DOI: 10.3969/j.issn.1006-6535.2022.01.018

References

[1] 曾宏斌,王芙蓉,罗京,等.基于低温氮气吸附和高压压汞表征潜江凹陷盐间页岩油储层孔隙结构特征[J].地质科技通报,2021,40(5):242-252.
ZENG Hongbin,WANG Furong,LUO Jing,et al.Characteristics of pore structure of intersalt shale oil reservoir by low temperature nitrogen adsorption and high pressure mercury pressure methods in Qianjiang Sag[J].Bulletin of Geological Science and Technology,2021,40(5):242-252.
[2] GAMADI T D,SHENG J J,SOLIMAN M Y,et al.An experimental study of cyclic CO2 injection to Improve shale oil recovery[C].SPE169142,2014:1-9.
[3] GAMADI T D,SHENG J J,SOLIMAN M Y.An experimental study of cyclic gas Injection to Improve shale oil recovery[C].SPE166334,2013:1-9.
[4] 张军,李桂菊.二氧化碳封存技术及研究现状[J].能源与环境,2007,41(2) :33-35.
ZHANG Jun,LI Guiju.Carbon dioxide sequestration technology and research status[J].Energy and Environment,2007,41(2):33-35.
[5] 张二勇.澳大利亚Otway盆地二氧化碳地质封存示范工程[J].水文地质工程地质,2012,39(2):135-137.
ZHANG Eryong.Introduction to the CO2 geosequestration demonstration project in the Otway Basin in Australia[J].Hydrogeology & Engineering Geology,2012,39(2):135-137.
[6] BACHU S.Sequestration of CO2 geological media:criteria and approach for site selection in response to climate change[J].Energy convers manage,2000,41(9):953-970.
[7] GALE J,CHRISTENSEN N P,CUTLER A,et al.Demonstrating the potential for geological storage of CO2:the sleipner and GESTCO projects[J].Environmental geosciences,2001,8(3):160-165.
[8] JIA B,TSAU J S,BARATI R.Role of molecular diffusion in heterogen eous,naturally fractured shale reservoirs during CO2 huff-n-prff[J].Journal of Petroleum Science and Engineering,2018,164(S1):31-42.
[9] CHEN C,BALHOFF M T,MOHANTY K K.Effect of reservoir heterogeneity on primary recovery and CO2 huff-n-puff recovery in shale-oil reservoirs[J].SPE Reservoir Evaluation & Engineering,2014,17(3):404-413.
[10] LI L,WANG C,LI D,et al.Experimental investigation of shale oil recovery from Qianjiang core samples by the CO2 huff-n-puff EOR method[J].RSC Adv,2019,9(49):28857-28869.
[11] LI L,SU Y,SHENG J J,et al.Experimental and numerical study on CO2 sweep volume during CO2 huff-n-puff enhanced oil recovery process in shale oil reservoirs[J].Energy & Fuels,2019,33(5):4017-4032.
[12] WANG X,XIAO P,YANG Z,et al.Laboratory and field-scale parameter optimization of CO2 huff-n-puff with the staged-fracturing horizontal well in tight oil reservoirs[J].Journal of Petroleum Science and Engineering,2020,186(2):106703.
[13] XIAO P,CUI M,ZHANG W,et al.Experimental and dimensional analysis of CO2-assisted gravity drainage in low permeability dip reservoirs of east China[J].Energy Sources,Part A:Recovery,Utilization,and Environmental Effects,2020,42(20):1-11.
[14] XIAO P,LYU C,WANG R,et al.Laboratory study heterogeneity impact on microscopic residual oil distribution in tight sandstone cores during CO2 immiscible flooding[J].Energy Sources,Part A:Recovery,Utilization,and Environmental Effects,2019,41(23):2895-2905.
[15] EDLMANN K,HINCHLIFFE S,HEINEMANN N,et al.Cyclic CO2-H2O injection and residual trapping: implications for CO2 injection efficiency and storage security[J].International Journal of Greenhouse Gas Control,2019,80:1-9.
[16] HARRISON A L,JEW A D,DUSTIN M K,et al.Element release and reaction-induced porosity alteration during shale-hydraulic fracturing fluid interactions[J].Applied Geochemistry,2017,82:47-62.
[17] 王秀宇,杨胜来,杨永忠,等.CO2封存和提高采收率过程中岩石与饱和水的CO2反应研究[J].钻采工艺,2015,38(3):87-90.
WANG Xiuyu,YANG Shenglai,YANG Yongzhong,et al.Reactivity of rock in water-saturated CO2 during carbon dioxide storage and enhanced oil recovery[J].Drilling & Production Technology,2015,38(3):87-90.
[18] 徐永强,李紫晶,郭翼隆,等.页岩储层-超临界CO2-模拟压裂液相互作用实验研究及其环境意义[J].地学前缘,2018,25(4):245-254.
XU Yongqiang,LI Zijing,GUO Yilong,et al.Experimental study on the shale reservoir-supercritical CO2-simulated fracturing fluid interaction and its environmental significance[J].Earth Science Frontiers,2018,25(4):245-254.
[19] SANGUINITO S,CVETIC P,GOODMAN A,et al.Characterizing pore-scale geochemical alterations in Eagle Ford and Barnett Shale from exposure to hydraulic fracturing fluid and CO2/H2O[J].Energy & Fuels,2021,35(1):583-598.
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