Reservoir Engineering

Study of the CO2-C2H6 enhanced crude oil extraction and miscibility

  • WANG Chengwei ,
  • SU Yuliang ,
  • WANG Wendong ,
  • LI Lei ,
  • HAO Yongmao
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  • 1. School of Petroleum Engineering,China University of Petroleum (East China),Qingdao,Shandong 266580, China;
    2. Key Laboratory of Unconventional Oil and Gas Development,Ministry of Education,China University of Petroleum (East China),Qingdao,Shandong 266580, China

Received date: 2024-03-12

  Revised date: 2024-11-07

  Online published: 2025-05-13

Abstract

In response to the unclear understanding of the synergistic mechanism of CO2-C2H6 and the variation in miscibility during the tight reservoir development,high-temperature and high-pressure PVT device was utilized to conduct oil and gas phase behavior and extraction experiments.The study investigated the phase behavior and extraction characteristics between CO2-C2H6 mixture and crude oil,and simulated the occurrence status and the mixed-phase pressure change characteristics by molecular dynamics.The study shows that:compared with the injection of CO2 only,the addition of ethane results in a decrease of about 0.1% in the high carbon molecular weight percentage of crude oil.Ethane can effectively enhance the extraction capability of the injected gas on crude oil,transforming high carbon hydrocarbons into lower carbon hydrocarbons such as C5.Both CO2 and CO2-C2H6 mixture are capable of extracting C2,C4,and C6 from multi-component oil molecules into the gas phase,lowering the intermolecular forces in the oil phase and enhancing the mobility of crude oil.The diffusion and miscibility capabilities of the gas mixture in crude oil are stronger than those of pure CO2.The gas mixture is more likely to form miscibility with crude oil,thereby increasing the degree of oil production.This study provides theoretical guidance for the synergistic enhanced recovery technology of CO2-C2H6 gas mixture injection in tight oil reservoirs.

Cite this article

WANG Chengwei , SU Yuliang , WANG Wendong , LI Lei , HAO Yongmao . Study of the CO2-C2H6 enhanced crude oil extraction and miscibility[J]. Special Oil & Gas Reservoirs, 2025 , 32(1) : 113 -119 . DOI: 10.3969/j.issn.1006-6535.2025.01.013

References

[1] 杨伟华,胡方芳,王蒙,等.致密油藏开发特征及开发技术研究[J].石油化工应用,2024,43(10):27-29.
YANG Weihua,HU Fangfang,WANG Meng,et al.Research on development characteristics and technology of tight oil reservoirs[J].Petrochemical Industry Application,2024,43(10):27-29.
[2] 王琛,高辉,费二战,等.鄂尔多斯盆地长7页岩储层压裂液渗吸规律及原油微观动用特征[J].中国石油大学学报(自然科学版),2023,47(6):95-103.
WANG Chen,GAO Hui,FEI Erzhan,et al.Imbibition of fracturing fluid and microscopic oil production characteristics in Chang 7 shale reservoir in Ordos Basin[J].Journal of China University of Petroleum(Edition of Natural Sciences),2023,47(6):95-103.
[3] 何登发,贾承造,赵文智,等.中国超深层油气勘探领域研究进展与关键问题[J].石油勘探与开发,2023,50(6):1162-1172.
HE Dengfa,JIA Chengzao,ZHAO Wenzhi,et al.Research progress and key issues of ultra-deep oil and gas exploration in China[J].Petroleum Exploration and Development,2023,50(6):1162-1172.
[4] 王浩栋,展转盈,安泽鹏.低渗致密油藏开发技术的研究进展[J].当代化工研究,2023,10(20):29-31.
WANG Haodong,ZHAN Zhuanying,AN Zepeng.Research progress on development technology of low permeability tight reservoir[J].Modern Chemical Research,2023,10(20):29-31.
[5] 张兴文,王拓夫,闫家宁,等.鄂尔多斯盆地延长组致密油储集层特征研究[J].粘接,2023,50(5):107-111.
ZHANG Xingwen,WANG Tuofu,YAN Jianing,et al.Reservoir characteristics of Yanchang Formation tight oil reservoirs in Ordos Basin[J].Adhesion,2023,50(5):107-111.
[6] 王国栋,沈瑞,郭和坤,等.致密油赋存状态影响因素及表征方法研究现状综述[J].应用化工,2023,52(3):855-860.
WANG Guodong,SHEN Rui,GUO Hekun,et al.Review on the research status of influencing factors and characterization methods of tight oil occurrence[J].Applied Chemical Industry,2023,52(3):855-860.
[7] 吴春燕,王宁,白薷,等.新安边地区长7致密油储层孔隙结构对可动流体赋存的影响[J].西北大学学报(自然科学版),2022,52(2):318-326.
WU Chunyan,WANG Ning,BAI Ru,et al.Effect of pore structure on the occurrence of movable fluid in Chang 7 tight oil reservoir in Xin′anbian Area[J].Journal of Northwest University(Natural Science Edition),2022,52(2):318-326.
[8] 高攀明,李烨炜.鄂尔多斯盆地周长区长7致密油储层特征及影响因素[J].化工管理,2021,34(13):94-95.
GAO Panming,LI Yewei.Characteristics and influence factor of Chang 7 tight oil reservoir in Zhouchang Area,Ordos Basin[J].Chemical Enterprise Management,2021,34(13):94-95.
[9] 蒋天昊,宋方新,朱陇新,等.鄂尔多斯盆地华池地区长62储层特征研究与评价[J].石油化工应用,2023,42(12):70-75.
JIANG Tianhao,SONG Fangxin,ZHU Longxin,et al.Research and evaluation of Chang 62 reservoir characteristics in Huachi Area,Ordos Basin[J].Petrochemical Industry Application,2023,42(12):70-75.
[10] 魏兵,王怡文,赵金洲,等.固液界面特征对致密/页岩储层渗吸行为的影响——以延长组7段+8段致密储层和龙马溪组页岩为例[J].石油学报,2023,44(10):1683-1692.
WEI Bing,WANG Yiwen,ZHAO Jinzhou,et al.Influence laws of solid-liquid interface characteristics on the imbibition behaviors of tight/shale reservoirs:a case study of tight reservoirs in Member 7 and 8 of Yanchang Formation and shale reservoirs in Longmaxi Formation[J].Acta Petrolei Sinica,2023,44(10):1683-1692.
[11] 王雨菡,丁伟铭,刘璇,等.渤海湾盆地渤南洼陷沙河街组三段下亚段岩相特征及有机质富集成因[J].石油与天然气地质,2019,40(5):1106-1114.
WANG Yuhan,DING Weiming,LIU Xuan,et al.Lithofacies and causal mechanism of organic matter enrichment in the lower submember of the 3rd member of Shahejie Formation,Bonan Sag,Bohai Bay Basin[J].Oil & Gas Geology,2019,40(5):1106-1114.
[12] 王蓓,胡艺潇,周伟,等.玛西斜坡百口泉组致密砂砾岩储层速敏特征及主控因素[J].中国石油大学学报(自然科学版),2024,48(4):141-148.
WANG Bei,HU Yixiao,ZHOU Wei,et al.Velocity-sensitive characteristics and main controlling factors of tight glutenite reservoirs in Baikouquan Formation of Maxi Slope[J].Journal of China University of Petroleum(Edition of Natural Sciences),2024,48(4):141-148.
[13] 胡泽根,马宇奔,李明峰,等.致密油提高采收率技术研究进展[J].石油化工应用,2023,42(3):5-11.
HU Zegen,MA Yuben,LI Mingfeng,et al.Research progress on enhanced oil recovery technology of tight oil[J].Petrochemical Industry Application,2023,42(3):5-11.
[14] HAN B,CUI G,WANG Y,et al.Effect of fracture network on water injection huff-puff for volume stimulation horizontal wells in tight oil reservoir:field test and numerical simulation study[J].Journal of Petroleum Science and Engineering,2021,207:109106.
[15] ZHAO J,FAN J,HE Y,et al.Optimization of horizontal well injection-production parameters for ultra-low permeable-tight oil production:a case from Changqing Oilfield,Ordos Basin,NW China[J].Petroleum Exploration and Development,2015,42(1):74-82.
[16] LI S,YANG S,DONG W,et al.Influence of water injection pressure and method on oil recovery of water injection huff and puff in tight volcanic Oil reservoirs[J].ACS omega,2022,7(25):21595-21607.
[17] 孙靖,齐洪岩,薛晶晶,等.准噶尔盆地深层—超深层致密砾岩储层特征及控制因素[J].天然气工业,2023,43(8):26-37.
SUN Jing,QI Hongyan,XUE Jingjing,et al.Characteristics and controlling factors of deep and ultra deep tight conglomerate reservoirs in the Junggar Basin[J].Natural Gas Industry,2023,43(8):26-37.
[18] YU W,LASHGARI H R,WU K,et al.CO2 injection for enhanced oil recovery in Bakken tight oil reservoirs[J].Fuel,2015,159:354-363.
[19] YU H,FU W,ZHANG Y,et al.Experimental study on EOR performance of CO2-based flooding methods on tight oil[J].Fuel,2021,290:119988.
[20] ZHANG Y,YU W,LI Z,et al.Simulation study of factors affecting CO2 huff-n-puff process in tight oil reservoirs[J].Journal of Petroleum Science and Engineering,2018,163:264-269.
[21] ZHANG J,ZHANG H X,MA L Y,et al.Performance evaluation and mechanism with different CO2 flooding modes in tight oil reservoir with fractures[J].Journal of Petroleum Science and Engineering,2020,188:106950.
[22] REN D,WANG X,KOU Z,et al.Feasibility evaluation of CO2 EOR and storage in tight oil reservoirs:a demonstration project in the Ordos Basin[J].Fuel,2023,331:125652.
[23] 朱清源,吴克柳,张晟庭,等.致密砂岩气藏注CO2提高天然气采收率微观机理[J].天然气工业,2024,44(4):135-145.
ZHU Qingyuan,WU Keliu,ZHANG Shengting,et al.Microscopic mechanism of CO2 injection to enhance gas recovery in tight sandstone gas reservoirs[J].Natural Gas Industry,2024,44(4):135-145.
[24] 唐维宇.致密油藏注气提高采收率潜力研究[D].北京:中国石油大学(北京),2021.
TANG Weiyu.Potential study on gas injection for enhanced oil recovery in tight oil reservoirs[D].Beijing:China University of Petroleum(Beijing),2021.
[25] 刘涛,李宜强,刘哲宇,等.致密油减氧空气吞吐开发储层伤害特征[J].成都理工大学学报(自然科学版),2023,50(3):324-332.
LIU Tao,LI Yiqiang,LIU Zheyu,et al.Study on reservoir damage characteristics of tight oil oxygen reduction air huff and puff development[J].Journal of Chengdu University of Technology(Science & Technology Edition),2023,50(3):324-332.
[26] 马欣健,向祖平,朱诗杰,等.四川盆地页岩储层中CO2/CH4竞争吸附规律的影响因素[J].天然气勘探与开发,2023,46(3):117-122.
MA Xinjian,XIANG Zuping,ZHU Shijie,et al.Influential factors on competitive adsorption between CO2 and CH4 in shale reservoirs of Sichuan Basin[J].Natural Gas Exploration and Development,2023,46(3):117-122.
[27] 张一帆,王璐,邹瑞,等.助溶剂对二氧化碳置换页岩油及碳封存的影响[J].石油勘探与开发,2023,50(6):1318-1326.
ZHANG Yifan,WANG Lu,ZOU Rui,et al.Effect of cosolvents on CO2 displacement of shale oil and carbon storage[J].Petroleum Exploration and Development,2023,50(6):1318-1326.
[28] 石阳,许可,翁定为,等.基于分子动力学模拟的改性部分水解聚丙烯酰胺耐温机理[J].石油与天然气化工,2023,52(3):76-80,86.
SHI Yang,XU Ke,WENG Dingwei,et al.Temperature resistance mechanism of modified partially hydrolyzed polyacrylamide based on molecular dynamics simulation[J].Chemical Engineering of Oil & Gas,2023,52(3):76-80,86.
[29] 王顺,王敬,刘慧卿,等.表面活性剂辅助残余油剥离机制的分子模拟[J].石油学报,2023,44(3):518-533.
WANG Shun,WANG Jing,LIU Huiqing,et al.Molecular simulation on the detachment mechanism of residual oil with the aid of surfactant[J].Acta Petrolei Sinica,2023,44(3):518-533.
[30] 张军,房体明,王业飞,等.烷烃油滴在超临界二氧化碳中溶解的分子动力学模拟[J].中国石油大学学报(自然科学版),2015,39(2):124-129.
ZHANG Jun,FANG Timing,WANG Yefei,et al.Molecular dynamics simulation of dissolution of n-alkanes droplets in supercritical carbon dioxide[J].Journal of China University of Petroleum(Edition of Natural Sciences),2015,39(2):124-129.
[31] 余涛,李琦,谭永胜,等.基于分子动力学方法的致密砂岩储层CO2驱油研究进展[J].天然气工业,2024,44(4):146-159.
YU Tao,LI Qi,TAN Yongsheng,et al.Research progress of CO2 flooding in tight sandstone reservoirs based on molecular dynamics method[J].Natural Gas Industry,2024,44(4):146-159.
[32] 魏兵,陈海龙,刘帅,等.页岩储层CO2吸附解吸行为及弥散特征[J].天然气工业,2024,44(12):176-186.
WEI Bing,CHEN Hailong,LIU Shuai,et al.CO2 adsorption/desorption behaviors and dispersion characteristics in shale reservoirs[J].Natural Gas Industry,2024,44(12):176-186.
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