纳米材料提高油气采收率技术研究及应用

doi:10.3969/j.issn.1006-6535.2020.06.006

摘要/Abstract

摘要： 结合近20 a来国内外纳米材料矿场应用案例,从纳米材料的分类和驱油机理2个方面进行了梳理及论述,对纳米材料在提高油气采收率的技术优势及存在问题进行了分析,探讨并展望了未来纳米材料应用于提高采收率领域的关键与发展方向。目前应用于提高采收率的纳米颗粒按材料主要分为金属氧化物、有机颗粒和无机颗粒3类;纳米材料的驱油机理通常是多种机理的结合;片状纳米材料具有独特优势,其中,新型2D智能纳米驱油技术已成功开展了多次矿场试验,在提高采收率领域的应用潜力巨大。

关键词: 纳米材料, 提高采收率, 油气田开发, 黑卡, 化学驱, 低渗油藏

Abstract: Combined with the field application cases at home and abroad in the past 20 years, the classification and oil displacement mechanism of nano-materials were analyzed and discussed. the technical advantages and problems of nano-materials in enhanced oil recovery were analyzed. The key factors and development direction of nano-materials applied in the field of enhanced oil recovery in the future were discussed and prospected. At present, the nano-particles used in enhanced oil recovery can be divided into metal oxides, organic particles and inorganic particles. The oil displacement mechanism of nano-materials is usually a combination of various mechanisms. Lamellar nano-materials have unique advantages. Hereinto, the new 2D intelligent nano oil displacement technology has been successfully carried out in many field tests and has great application potential in the field of enhancing oil recovery.

Key words: nano-materials, enhanced oil recovery, oil and gas field development, Black Card, chemical flooding, low-permeability oil reservoir

中图分类号:

TE357

侯吉瑞, 闻宇晨, 屈鸣, 吴文明, 张炜, 丁乙桐. 纳米材料提高油气采收率技术研究及应用[J]. 特种油气藏, 2020, 27(6): 47-53.

Hou Jirui, Wen Yuchen, Qu Ming, Wu Wenming, Zhang Wei, Ding Yitong. Research and Application of Nano-materials to Enhance Oil and Gas Recovery Technology[J]. Special Oil & Gas Reservoirs, 2020, 27(6): 47-53.

参考文献

[1] 冯涛,柳迎斌,舒通燕,等.纳米液在提高采收率中的应用[J].内蒙古石油化工,2008,34(5):25-27.
FENG Tao,LIU Yingbin,SHU Tongyan,et al.Application of nanometer liquid in improving oil recovery[J].Inner Mongolia Petrochemical Industry,2008,34(5):25-27.
[2] 柯扬船,魏光耀.纳米材料在石油天然气田开发中的应用进展[J].油田化学,2008,25(2):189-192.
KE Yangchuan,WEI Guangyao.Application and development of nanomaterials in oil drilling and recovery[J].Oilfield Chemistry,2008,25(2):189-192.
[3] MUSTAFA A,BAI B J.The synergistic effects of nanoparticle-surfactant nanofluids in EOR applications[J].Journal of Petroleum Science and Engineering,2018,171:196-210.
[4] ALI J A,KOLO K,MANSHAD A K,et al.Recent advances in application of nanotechnology in chemical enhanced oil recovery:effects of nanoparticles on wettability alteration,interfacial tension reduction,and flooding[J].Egyptian Journal of Petroleum,2018,27:1371-1383.
[5] OGOLO N A,OLAFUYI O A,ONYEKONWU M O.Enhanced oil recovery using nanoparticles [C].SPE160847,2012:1-9.
[6] HENDRANINGRAT L,TORSATER O.Metal oxide-based nanoparticles:revealing their potential to enhance oil recovery in different wettability systems[J].Applied Nanoscience,2015,5(2):181-199.
[7] SHAH R D.Application of nanoparticle saturated injectant gases for EOR of heavy oils[C].SPE129539-STU,2009:12-24.
[8] KOTHARI N,RAINA B,CHANDAK K,et al.Application of ferrofluid for enhanced surfactant flooding in IOR[C].SPE131272,2010:1-7.
[9] CHANDRAN K.Multiwall carbon nanotubes (MWNT) fluid in EOR under the presence of electromagnetic waves[D].Perak:Petronas University of Technology,2013.
[10] WANG L W,WANG Z C,YANG H,et al.The study of thermal stability of the SiO₂ powders with high specific surface area[J].Materials Chemistry and Physics,1999,57(3):260-263.
[11] YOUSSIF M I,ELMAGHRABY R M,SALEH S M,et al.Silica nanofluid flooding for enhanced oil recovery in sandstone rocks[J].Egyptian Journal of Petroleum,2018,27(1):105-110.
[12] MIRANDA C R,LARA L S D,TONETTO B C.Stability and mobility of functionalized silica nanoparticles for enhanced oil recovery applications[C].SPE157033,2012:1-11.
[13] SINGH R,MOHANTY K K.Foams stabilized by in-situ surface activated nanoparticles in bulk and porous media[J].SPE Journal,2016,21(1):121-130.
[14] NGUYEN P T,DO B P H,PHAM D K,et al.Evaluation on the EOR potential capacity of the synthesized composite silica-core/polymer-shell nanoparticles blended with surfactant systems for the HPHT off shore reservoir conditions[C].SPE157127,2012:1-10.
[15] RAJ I,QU M,XIAO L Z,et al.Ultralow concentration of molybdenum disulfide nanosheets for enhanced oil recovery[J].Fuel,2019,251:514-522.
[16] SKAUGE T,SPILDO K,SKAUGE A.Nano-sized particles for EOR[C].SPE129933,2010:1-10.
[17] SHAMSIJAZEYI H,MILLER C A,WONG M,et al.Polymer-coated nanoparticles for enhanced oil recovery[J].Journal of Applied Polymer Science,2014,131(15):4401-4404.
[18] WANG L,ZHANG G,JIANG G E,et al.Preparation of microgel nanospheres and their application in EOR[C].SPE130357,2010:1-7.
[19] KAZEMZADEH Y,SHOJAEI S,RIAZI M,et al.Review on application of nanoparticles for EOR purposes:a critical review of the opportunities and challenges[J].Chinese Journal of Chemical Engineering,2019,27(2):237-246.
[20] AVEYARD R,BINKS B P,CLINT J H.Emulsions stabilised solely by colloidal particles[J].Advances in Colloid and Interface Science,2003,100(1):503-546.
[21] CHENGARA A,NIKOLOV A D,WASAN D T,et al.Spreading of nanofluids driven by the structural disjoining pressure gradient[J].Journal of Colloid and Interface Science,2004,280(1):192-201.
[22]ROUSTAEI A,MOGHADASI J,BAGHERZADEH H,et al.An experimental investigation of polysilicon nanoparticles′ recovery efficiencies through changes in interfacial tension and wettability alteration[C].SPE156976,2012:1-7.
[23] WANG D Y,DUAN H W,MOHWALD H.The water/oil interface:the emerging horizon for self-assembly of nanoparticles[J].Soft Matter,2005,1(6):412-416.
[24] MAGHZI A,MOHEBBI A,KHARRAT R,et al.Pore-scale monitoring of wettability alteration by silica nanoparticles during polymer flooding to heavy oil in a five-spot glass micromodel[J].Transport in Porous Media,2011,87:653-664.
[25] HENDRANINGRAT L,LI S D,TORSATER O.A coreflood investigation of nanofluid enh-anced oil recovery[J].Journal of Petroleum Science and Engineering,2013,111:128-138.
[26] HAROUN M R,ALHASSAN S,ANSARI A A,et al.Smart nano-EOR process for Abu Dhabi carbonate reservoirs[C].SPE162386,2012:1-13.
[27] METIN C O,RANKIN K M,NGUYEN Q P.Phase behavior and rheological characterization of silica nanoparticle gel[J].Applied Nanoscience,2014,4(1):93-101.
[28] 刘高友,郭雄华,程芙蓉,等.一种纳米级阻聚堵水材料的试验研究[J].江汉石油学院学报,2003,25(增刊2):147-148.
LIU Gaoyou,GUO Xionghua,CHENG Furong,et al.Test of nano-grade polymerization inhibition and water-blocking material[J].Journal of Jianghan Petroleum Institute,2003,25(S2):147-148.
[29] 陈渊,陈旭,刘卫军.纳米堵剂在河南油田高压注水井简化管柱上的研究与应用[J].特种油气藏,2008,15(1):92-94,98.
CHEN Yuan,CHEN Xu,LIU Weijun.Study and application of nanometer blocking agent in high pressure injectors in Henan Oilfield[J].Special Oil ＆ Gas Reservoirs,2008,15(1):92-94,98.
[30] 曲海莹,刘琦,彭勃,等.纳米颗粒对CO₂泡沫体系稳定性的影响[J].油气地质与采收率,2019,26(5):120-126.
QU Haiying,LIU Qi,PENG Bo,et al.Effect of nanoparticle on stability of CO₂ foam flooding system[J].Petroleum Geology and Recovery Efficiency,2019,26(5):120-126.
[31] 张德华.聚硅纳米增注技术在纯梁油区低渗透油田的应用[J].内蒙古石油化工,2013,39(10):100-101.
ZHANG Dehua.Application of polysilicon nano-injection technology in low permeability oilfields in Chunliang oil area[J].Inner Mongolia Petrochemical Industry,2013,39(10):100-101.
[32] 郭小哲,韩文磊,牛慧珍,等.基于专利分析的纳米采油技术发展趋势[J].石油科技论坛,2017,36(3):32-40,49.
GUO Xiaozhe,HAN Wenlei,NIU Huizhen,et al.Development trend for nanometer oil production technology based on patent analysis[J].Petroleum Science and Technology Forum,2017,36(3):32-40,49.