特种油气藏 ›› 2020, Vol. 27 ›› Issue (6): 133-138.DOI: 10.3969/j.issn.1006-6535.2020.06.019

• 油藏工程 • 上一篇    下一篇

稠油活化剂降黏机理及驱油效果研究

王旭东1,2, 张健1,2, 施雷庭3, 赵娟1,2, 杨光1,2, 梁旭伟3   

  1. 1.海洋石油高效开发国家重点实验室,北京 100028;
    2.中海石油(中国)有限公司北京研究中心,北京 100028;
    3.西南石油大学油气藏地质及开发工程国家重点实验室,四川 成都 610500
  • 收稿日期:2020-05-22 修回日期:2020-08-31 出版日期:2020-12-25 发布日期:2022-02-18
  • 通讯作者: 施雷庭(1976—),男,副教授,2000年毕业于西南石油学院石油工程专业,2007年毕业于西南石油大学油气田开发工程专业,获博士学位,现从事提高采收率方向的教学和科研工作。
  • 作者简介:王旭东(1986—),男,高级工程师,2008年毕业于大庆石油学院石油工程专业,2012年毕业于中国石油大学(北京)油气田开发工程专业,获硕士学位,现从事油田开发和提高采收率研究工作。
  • 基金资助:
    中海石油(中国)有限公司重大项目“渤海油田化学驱提高采收率技术”(CNOOC-KJ135ZDXM36TJ02ZY)

Study on Viscosity Reduction Mechanism and Oil Displacement Effect of Heavy Oil Activator

Wang Xudong1,2, Zhang Jian1,2, Shi Leiting3, Zhao Juan1,2, Yang Guang1,2, Liang Xuwei3   

  1. 1. State Key Laboratory of Efficient Development of Offshore Oil, Beijing 100028, China;
    2. Beijing Research Center of CNOOC (China) Co., Ltd., Beijing 100028, China;
    3. State Key Laboratory of Oil and Gas Reservoir Geology and Exploration, Southwest Petroleum University, Chengdu, Sichuan 610500, China
  • Received:2020-05-22 Revised:2020-08-31 Online:2020-12-25 Published:2022-02-18

摘要: 稠油降黏冷采是海上油田开发的主要方式,为深入认识稠油活化剂的降黏机理及其在原油黏度为150~1 000 mPa·s的稠油油藏中的应用效果,通过室内物理模拟实验和耗散粒子动力学模拟技术,研究了稠油活化剂对稠油的降黏机理及驱油效果。结果表明,稠油活化剂可提高水相黏度、降低油水界面张力,能有效降低常规可流动稠油的黏度。分子尺度上的研究结果显示,稠油活化剂分子对沥青质聚集体有明显的阻聚-分散效果,其活性基团能增大沥青质芳香盘的层间距和链间距,减小沥青质聚集体堆积高度和堆积层数,削弱沥青质间的相互作用,破坏稠油重质组分聚集结构,分散稠油,从而增强原油流动能力。稠油活化剂的多种机理协同作用使其在室内岩心驱替实验和矿场应用中,均可起到良好的降水增油效果。该研究从分子层面明确了活化剂降低稠油黏度机理,为稠油活化剂现场应用提供理论指导。

关键词: 稠油活化剂, 降黏机理, 拆解降黏, 沥青质聚集体, 分子模拟, 提高采收率

Abstract: Viscosity reduction and cold production of heavy oil is the main method for offshore oilfield development. In order to deeply understand the viscosity reduction mechanism and application effect of heavy oil activator in heavy oil reservoirs with crude oil viscosity ranging from 150 mPa·s to 1 000 mPa·s, by means of indoor physical simulation experiment and dissipative particle dynamics simulation technology, the viscosity reduction mechanism and displacement effect of the activator on heavy oil was studied. The results show that the heavy oil activator can increase the viscosity of the water phase, reduce the oil-water interfacial tension, and can effectively reduce the viscosity of the conventional flowable heavy oil. The research results on the molecular scale show that the molecule of heavy oil activator has a significant inhibitory-dispersing effect on asphaltene aggregates. The active groups in the activator molecule can increase the interlayer spacing and chain spacing of the aromatic hydrocarbon in asphaltene, reduce the asphaltene aggregation height and layers, weaken the interaction among asphaltenes, destroy the aggregation structure of the heavy components in heavy oil, and disperse the heavy oil, thereby enhancing the fluidity of crude oil. Whether in indoor core displacement experiments or in field applications, the synergistic effects of multiple mechanisms of heavy oil activators can achieve good water decrease and oil enhancement effects. From the molecular level, the study clarified the viscosity reduction mechanism of heavy oil activator, which can provide a theoretical guidance for the field application of heavy oil activator.

Key words: heavy oil activator, viscosity reduction mechanism, disassembled viscosity reduction, asphaltene aggregate, molecular simulation, oil recovery enhancement

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