储层矿物润湿性的测量方法综述

doi:10.3969/j.issn.1006-6535.2024.02.001

特种油气藏 ›› 2024, Vol. 31 ›› Issue (2): 1-9.DOI: 10.3969/j.issn.1006-6535.2024.02.001

• 综述 • 下一篇

储层矿物润湿性的测量方法综述

施砍园^1,2, 陈君青^1,3,4, 庞雄奇^1,2, 姜福杰^1,2, 庞宏^1,2, 惠沙沙^1,2, 马奎友^1,2, 丛奇^1,4

1.油气资源与工程全国重点实验室,北京 102249;
2.中国石油大学(北京),北京 102249;
3.能源交叉学科基础研究中心,北京 102249;
4.油气光学探测技术重点实验室,北京 102249

收稿日期:2022-09-20 修回日期:2024-02-10 出版日期:2024-04-25 发布日期:2024-07-26
通讯作者: 陈君青(1987—),女,副教授,博士生导师,2009年毕业于中国石油大学(北京)地质工程专业,2020年毕业于该校地质资源与地质工程专业,获博士学位,现主要从事油气藏形成机理的科研工作。庞雄奇(1961—),男,教授,博士生导师,1982年毕业于江汉石油学院油气地质与勘探专业,1991年毕业于地质大学(北京)油气地质与勘探专业,获博士学位,现主要从事油气藏形成与分布预测方向的研究。
作者简介:施砍园(1996—),男,2020年毕业于西安石油大学资源勘查工程专业,现为中国石油大学(北京)地质资源与地质工程专业在读博士研究生,主要从事页岩油可动性方面的研究。
基金资助:
国家自然科学基金“咸化湖盆页岩润湿性及演化对含油性的影响机制”(42102145)

A Review of Methods for Measuring the Wettability of Reservoir Minerals

Shi Kanyuan^1,2, Chen Junqing^1,3,4, Pang Xiongqi^1,2, Jiang Fujie^1,2, Pang Hong^1,2, Hui Shasha^1,2, Ma Kuiyou^1,2, Cong Qi^1,4

1. National Key Laboratory of Petroleum Resources and Engineering, Beijing 102249, China;
2. China University of Petroleum (Beijing), Beijing 102249, China;
3. Basic Research Center for Energy Interdisciplines, Beijing 102249, China;
4. Key Laboratory of Oil and Gas Optical Detection Technology, Beijing 102249, China

Received:2022-09-20 Revised:2024-02-10 Online:2024-04-25 Published:2024-07-26

摘要/Abstract

摘要： 储集岩的润湿性对孔隙中流体的分布与流动至关重要,关系到油气田提高采收率措施的选择及其实施效果,由于地下油气储层中矿物成分复杂、流体组成多样,目前尚无统一的储层岩石润湿性测量标准,根据油藏的具体条件选择合适的润湿性测量方法对石油开采至关重要。基于此,从物理实验与数值模拟两方面详细讨论了国内外目前使用较广且最新的测量岩石润湿性的方法,针对这些方法的原理、优缺点及适用条件进行总结,并对润湿性测量方法进行了展望。该研究有助于优选适用的润湿性测量方法,可为提高储层中岩石润湿性表征的准确性提供借鉴。

关键词: 润湿性, 润湿角, 矿物, 实验测量, 数值模拟

Abstract: The wettability of the reservoir rock is crucial to the distribution and flow of fluids in the pore, which is related to the selection of measures to improve the recovery rate of oil and gas fields and the effect of their implementation. Due to the complexity of the mineral composition and the diversity of the fluid composition in the underground oil and gas reservoir, there is no uniform standard for measuring the wettability of reservoir rock, and the selection of a suitable wettability measurement method according to the specific conditions of the reservoir is crucial to the oil production. Based on this, the most recent and widely used methods for rock wettability measurement at home and abroad were discussed in details in terms of physical experiments and numerical simulations, and the principles, advantages and disadvantages, and applicable conditions of these methods were summarized, and an outlook of the wettability measurement methods was also given. The study helps to select the applicable wettability measurement methods, which can provide a reference for improving the accuracy of rock wettability characterization in reservoirs.

Key words: wettability, wetting angle, minerals, experimental measurement, numerical simulation

中图分类号:

TE135

施砍园, 陈君青, 庞雄奇, 姜福杰, 庞宏, 惠沙沙, 马奎友, 丛奇. 储层矿物润湿性的测量方法综述[J]. 特种油气藏, 2024, 31(2): 1-9.

Shi Kanyuan, Chen Junqing, Pang Xiongqi, Jiang Fujie, Pang Hong, Hui Shasha, Ma Kuiyou, Cong Qi. A Review of Methods for Measuring the Wettability of Reservoir Minerals[J]. Special Oil & Gas Reservoirs, 2024, 31(2): 1-9.

参考文献

[1] HAMANO Y,KUZUYAMA T,ITOH N,et al.Functional analysis of eubacterial diterpenecyclases responsible for biosynthesis of a diterpeneantibiotic,terpentecin[J].Journal of Biological Chemistry,2002,277(40):37098-37104.
[2] SHI K Y,CHEN J Q,PANG X Q,et al.Wettability of different clay mineral surfaces in shale:implications from molecular dynamics simulations[J].Petroleum Science,2023,20(2):689-704.
[3] 覃生高.储层孔隙分布及流体渗流特征的分形描述与应用[D].大庆:大庆石油学院,2010.
QIN Shenggao.Fractal description and application of reservoir pore distribution and fluid seepage characteristics[D].Daqing:Daqing Petroleum Institute,2010.
[4] 赵亚溥.表面与界面物理力学[M].北京:科学出版社,2012:563-565.
ZHAO Yapu.Physical mechanics of surfaces and interfaces[M].Beijing:Science Press,2012:563-565.
[5] KAISER N,CROLL A,SZOFRAN F R,et al.Wetting angle and surface tension of germanium melts on different substrate materials[J].Journal of Crystal Growth,2001,231(4):448-457.
[6] 秦之铮.利用接触角计测角评价油层润湿性[J].石油勘探与开发,1987,14(3):80-81.
QIN Zhizheng.Evaluation of oil formation wettability using contact goniometer angle measurements[J].Petroleum Exploration and Development,1987,14(3):80-81.
[7] 高之业,熊书苓,成雨,等.川南地区龙马溪组页岩储层水接触角及其稳定性影响因素[J].特种油气藏,2021,28(5):10-16.
GAO Zhiye,XIONG Shuling,CHENG Yu,et al.Water contact angle and its stability influencing factors of shale reservoirs in Longmaxi Formation,southern Sichuan[J].Special Oil & Gas Reservoirs,2021,28(5):10-16.
[8] DEZELLUS O,HODAJ F,RADO C,et al.Spreading of Cu-Si alloys on oxidized SiC in vacuum:experimental results and modelling-science direct[J].Acta Materialia,2002,50(5):979-991.
[9] 卢双舫,薛海涛,印兴耀,等.页岩油形成条件、赋存机理与富集分布[M].北京:石油工业出版社,2021:160-161.
LU Shuangfang,XUE Haitao,YIN Xingyao,et al.Formationconditions,occurrencemechanism,enrichment and distribution of shale oil[M].Beijing:Petroleum Industry Press,2021:160-161.
[10] KUBIAK K J,WILSON M C T,MATHIA T G,et al.Dynamics of contact line motion during the wetting of rough surfaces and correlation with topographical surface parameters[J].Scanning,2011,33(5):370-377.
[11] ANDREAS J M,HAUSER E A,TUCKER W B.Boundary tension by pendant dropsi[J].The Journal of Physical Chemistry,1938,42(8):1001-1019.
[12] 吴春正.页岩油赋存特征的分子动力学模拟[D].青岛:中国石油大学(华东),2018.
WU Chunzheng.Molecular dynamics simulation of shale oil occurrence characteristics[D].Qingdao:China University of Petroleum(East China),2018.
[13] 钱健行.润湿角测定装置设计及其应用研究[D].沈阳:东北大学,2014.
QIAN Jianxing.Research on the design and application of wetting angle determination device[D].Shenyang:Northeastern University,2014.
[14] WASHBURN E W.The dynamics of capillary flow[J].Physical Review Letters,1921,17(3):273-283.
[15] ZHANG X J,TIAN J,WANG L J,et al.Wettability effect of coatings on drag reduction and paraffin deposition prevention in oil[J].Journal of Petroleum Science & Engineering,2002,36(1/2):87-95.
[16] TIAB D,DONALDSON E C.Petrophysics:theory and practice of measuring reservoir rock and fluid transport properties[M].Gulfport:Gulf Professional Pub,2012:269-286.
[17] ABE K,TAKIGUCHI H,TAMADA K.Dynamic Contact angle measurement of Au(111)-thiol self-assembled monolayers by the wilhelmy plate method[J].Langmuir,2000,16(5):2394-2397.
[18] WANG X,MIN Q,ZHANG Z M,et al.Influence of head resistance force and viscous friction on dynamic contact angle measurement in Wilhelmy plate method[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2017,527(16):115-122.
[19] 刘晓磊,吴其辉,姚思远,等.接触角理论模型与测量方法[J].化工时刊,2020,34(8):11-14,41.
LIU Xiaolei,WU Qihui,YAO Siyuan,et al.Theoretical models and measurement methods of contact angle[J].Chemical Industry Times,2020,34(8):11-14,41.
[20] 李成.岩石混合润湿条件下提高采收率机理研究[D].大庆:大庆石油学院,2007.
LI Cheng.Research on the mechanism of enhanced recovery under mixed rock wetting conditions[D].Daqing:Daqing Petroleum Institute,2007.
[21] 陈蓉,曲志浩,赵阳.油层润湿性研究现状及对采收率的影响[J].中国海上油气地质,2001,31(5):51-56.
CHEN Rong,QU Zhihao,ZHAO Yang.The study history of reservoir wettability and its effect on recovery[J].China Offshore Oil and Gas(Geology),2001,31(5):51-56.
[22] MCCAFFERY F G.The effect of wettability on relative permeability andimbibition in porous miedia[D].Calgary:University of Calgary,1993.
[23] DONALDSON E C,THOMAS R D,LORENZ P B.Wettability determination and its effect on recovery efficiency[J].SPE Journal,1969,9(1):13-20.
[24] NORMANR.Physics and thermodynamics of capillary action in porous media[J].Industrial & Engineering Chemistry Research,1970,62(6):32-56.
[25] ALRATROUT A,RAEINI A Q,BIJELJIC B,et al.Automatic measurement of contact angle in pore-space images[J].Advances in Water Resources,2017,109(11):158-169.
[26] KLEINBERG R L,HORSFIELD M A.Transverse relaxation processes in porous sedimentary rock[J].Journal of Magnetic Resonance,1990,88(1):9-19.
[27] AL-GARADI K,EL-HUSSEINY A,ELSAYED M,et al.A rock core wettability index using NMR T₂ measurements[J].Journal of Petroleum Science and Engineering,2022,208(1):109386.
[28] BELTRÁN A,HERNÁNDEZ-DÍAZ D,CHÁVEZ O,et al.Experimental study of the effect of wettability on the relative permeability for air-water flow through porous media[J].International Journal of Multiphase Flow,2019,120(11):103091.
[29] BROOKS R H,COREY A T.Hydraulic properties of porous media[J].American Society of Agricultural and Biological Engineers,1964,7(1):26-28.
[30] MIRZAEI-PAIAMAN A,GHANBARIAN B.A note on dynamic rock typing and TEM-function for grouping,averaging and assigning relative permeability data to reservoir simulation models[J].Journal of Natural Gas Science and Engineering,2020,87(3):103789.
[31] MIRZAEI-PAIAMAN A,FARAMARZI-PALANGAR M,DJEZZAR S,et al.A new approach to measure wettability by relative permeability measurements[J].Journal of Petroleum Science and Engineering,2021,208(1):109191.
[32] CHEN X Y,KIANINEJAD A,DICARLO D A.An extended JBN method of determining unsteady-state two-phase relative permeability[J].Water Resources Research,2016,52(10):8374-8383.
[33] 高晓龙.纳米尺度固体材料表面润湿性的数值模拟表征方法及其尺度效应研究[D].大连:大连理工大学,2019.
GAO Xiaolong.Numerical simulation characterization method of surface wettability of nanoscale solid materials and its scale effect study[D].Dalian:Dalian University of Technology,2019.
[34] NOURGALIEV R R,DINH T N,THEOFANOUS T G,et al.The lattice Boltzmann equation method:theoreticalinterpretation,numerics and implications[J].International Journal of Multiphase Flow,2003,29(1):117-169.
[35] YU Y,LIU H H,LIANG D,et al.A versatile lattice Boltzmann model for immiscible ternary fluid flows[J].Physics of Fluids,2019,31(1):012108.
[36] SEMPREBON C,KRÜGER T,KUSUMAATMAJA H.Ternary free energy lattice Boltzmann model with tunable surface tensions and contact angles[J].Physical Review E,2015,93(3):1-13.
[37] SHI K Y,CHEN J Q,PANG X Q,et al.Average molecular structure model of shale kerogen:experimentalcharacterization,structuralreconstruction,and pyrolysis analysis[J].Fuel,2024,355:129474.
[38] ALDER B J,WAINWRIGHT T E.Phase transition for a hard sphere system[J].The Journal of Chemical Physics,1957,27(5):1208-1209.
[39] PLIMPTONS.Fast parallel algorithms for short-range molecular dynamics[J].Journal of Computational Physics,1995,117(1):1-19.
[40] CAO Z,JIANG H,ZENG J H,et al.Nanoscale liquid hydrocarbon adsorption on clay minerals:amolecular dynamics simulation of shale oils[J].Chemical Engineering Journal,2020,420(3):127578.
[41] CHEN Y Q,AMIR U,YOGARAJAH E,et al.Detecting pH and Ca²⁺ increase during low salinity waterflooding in carbonate reservoirs:implications for wettability alteration process[J].Journal of Molecular Liquids,2020,317(21):114003.
[42] SHI K Y,CHEN J Q,PANG X Q,et al.Effect of wettability of shale on CO₂ sequestration with enhanced gas recovery in shale reservoir:implications from molecular dynamics simulation[J].Journal of Natural Gas Science and Engineering,2022,107(11):104798.
[43] PAN B,LI Y J,ZHANG M S,et al.Effect of total organic carbon(TOC) content on shale wettability at high pressure and high temperature conditions[J].Journal of Petroleum Science and Engineering,2020,193(10):107374.
[44] 陈子慧,林军章,汪卫东,等.油藏微生物润湿改性机理研究进展[J].油气地质与采收率,2022,29(4):83-90.
CHEN Zihui,LIN Junzhang,WANG Weidong,et al.Research progress in microbial wettability alteration mechanisms in oil reservoir[J].Petroleum Geology and Recovery Efficiency,2022,29(4):83-90.
[45] 冯雪钢,岳湘安,安维青,等.特低渗透与中高渗透岩心润湿性对水驱特性影响的差异[J].油气地质与采收率,2022,29(2):94-99.
FENG Xuegang,YUE Xiang′an,AN Weiqing,et al.Difference in effects of wettability of ultra-low and medium-high permeability cores on waterflooding characteristics[J].Petroleum Geology & Recovery Efficiency,2022,29(2):94-99.
[46] 冯程, 樊海涛, 石玉江,等.润湿性影响下低渗透储层地层水矿化度预测——以鄂尔多斯盆地陇东地区三叠系延长组长8₁段为例[J].石油与天然气地质,2020,41(2):442-448.
FENG Cheng, FAN Haitao, SHI Yujiang, et al.Prediction for the formation water salinity in low-permeability reservoirs with complex wettability:a case study of the Triassic Chang 8₁ Member,Longdong Area,Ordos Basin[J].Oil & Gas Geology,2020,41(2):442-448.
[47] 高艳玲,吴克柳,陈掌星,等.页岩储层两相流体润湿滞后对流动阻力的影响[J]. 西南石油大学学报(自然科学版),2021,43(5):66-72.
GAO Yanling, WU Keliu, CHEN Zhangxing, et al.Effect of wetting hysteresis on flow resistance for two-phase fluid system in shale reservoirs[J].Journal of Southwest Petroleum University (Science & Technology Edition),2021,43(5):66-72.

储层矿物润湿性的测量方法综述

A Review of Methods for Measuring the Wettability of Reservoir Minerals

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