油藏工程

注蒸汽开发后油藏火驱原位制氢可行性

  • 王田田 ,
  • 赵仁保 ,
  • 蒋宁宁 ,
  • 李鑫 ,
  • 徐晗 ,
  • 王昊
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  • 1.中国石油大学(北京)油气资源与探测国家重点实验室,北京 102249;
    2.中国石油大学(北京)克拉玛依校区,新疆 克拉玛依 834000
王田田(1995—),女,2014年毕业于延安大学化学专业,现为中国石油大学(北京)石油与天然气工程专业在读博士研究生,主要从事稠油原位制氢的实验研究工作。

收稿日期: 2023-02-15

  修回日期: 2023-12-13

  网络出版日期: 2024-04-18

基金资助

国家自然科学基金“火线推进速度的预测和火腔在三维空间中演化的控制机制探索”(52274052);新疆维吾尔族自治区高层次人才引进项目“基于垂向火驱井网条件下超稠油的原位改质辅助开发机理研究”(JXDF0221)

Feasibility of In-Situ Hydrogen Production During Fire Flooding in Reservoirs after Steam Injection Development

  • Wang Tiantian ,
  • Zhao Renbao ,
  • Jiang Ningning ,
  • Li Xin ,
  • Xu Han ,
  • Wang Hao
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  • 1. State Key Laboratory of Oil and Gas Resources and Exploration of China University of Petroleum (Beijing), Beijing 102249, China;
    2. China University of Petroleum-Beijing at Karamay, Karamay, Xinjiang 834000, China

Received date: 2023-02-15

  Revised date: 2023-12-13

  Online published: 2024-04-18

摘要

针对注蒸汽开发后油藏中火驱原位制氢技术的可行性问题,通过燃烧管实验,开展了含水饱和度对稠油原位制氢效果的影响研究。结果表明:水的存在增强了对流传热效应,为碳氢化合物中C—C和C—H的断裂提供了高温环境;并促进了稠油水热裂解、焦炭气化、水汽变换等可逆反应向制氢方向移动,提高了制氢效果。在含水饱和度为24.58%时,温度最高达715.1 ℃,氢气体积分数最高为1.03%。研究结果验证了注蒸汽开发后稠油油藏火驱原位制氢的可行性,该研究对提高稠油火驱原位制氢效果具有重要参考价值。

本文引用格式

王田田 , 赵仁保 , 蒋宁宁 , 李鑫 , 徐晗 , 王昊 . 注蒸汽开发后油藏火驱原位制氢可行性[J]. 特种油气藏, 2024 , 31(1) : 81 -86 . DOI: 10.3969/j.issn.1006-6535.2024.01.010

Abstract

A study on the influence of water saturation on the in-situ hydrogen production effect from heavy oil was carried out through combustion tube experiments to study the feasibility of technology on in-situ hydrogen production during fire flooding in reservoirs after steam injection development. The results show that the presence of water enhances the convective heat transfer effect and provides a high-temperature environment for the fracture of C-C and C-H in hydrocarbons and promotes the reversible reactions such as hydrothermal cracking, coke gasification, and water-steam conversion of heavy oil to move toward hydrogen production, which improves the in-situ hydrogen production effect. The temperature is 715.1 ℃, and the hydrogen volume fraction is up to 1.03% when the water saturation reaches 24.58%. The results verified the feasibility of in-situ hydrogen production from heavy oil during fire flooding in heavy oil reservoirs after steam injection development, and the study has significant reference value for improving the in-situ hydrogen production effect from heavy oil during fire flooding.

参考文献

[1]HBA A, MA B.Prospect of hydrogen energy in Asia-Pacific: a perspective review on techno-socio-economy nexus[J].International Journal of Hydrogen Energy,2021,46(71):35027-35056.
[2]邹才能,熊波,薛华庆,等.新能源在碳中和中的地位与作用[J].石油勘探与开发,2021,48(2):411-420.
ZOU Caineng,XIONG Bo,XUE Huaqing,et al.The role of new energy in carbon neutral[J].Petroleum Exploration and Development,2021,48(2):411-420.
[3]杨洪,苏日古,陈莉娟,等.火驱原油活性氢组分变化规律认识[J].特种油气藏,2022,29(6):127-132.
YANG Hong,SU Rigu,CHEN Lijuan,et al.Recognition of variation law of active hydrogen component of fire-flooded crude oil[J].Special Oil & Gas Reservoirs,2022,29(6):127-132.
[4]KAPADIA P R, KALLOS M S, GATES I D.Potential for hydrogen generation from in situ combustion of Athabasca bitumen[J]. Fuel, 2011, 90(6): 2254-2265.
[5]唐君实,关文龙,蒋有伟,等.稀油火烧油层物理模拟[J].石油学报,2015,36(9):1135-1140.
TANG Junshi,GUAN Wenlong,JIANG Youwei,et al.Physical simulation of light oil in-situ combustion[J].Acta Petrolei Sinica,2015,36(9):1135-1140.
[6]YANG S,HUANG S,JIANG Q, et al.Experimental study of hydrogen generation from in-situ heavy oil gasification[J].Fuel, 2022, 313:1-12.
[7]KAPADIA P R,WANG J,KALLOS M S,et al.Practical process design for in-situ gasification of bitumen[J].Applied Energy, 2013, 107: 281-96.
[8]WANG W,GIANNI O,DACHAMIR H,et al.Inorganic membranes for in-situ separation of hydrogen and enhancement of hydrogen production from thermochemical reactions[J].Renewable and Sustainable Energy Reviews, 2022, 160: 1-18.
[9]ZHAO R, ZHANG C, YANG F X, et al.Influence of temperature field on rock and heavy components variation during in-situ combustion process[J].Fuel, 2018, 230:244-257.
[10] PHAM C Q, SIANG T J, KUMAR P S, et al.Generation of hydrogen and value-added carbon materials by catalytic methane decomposition: a review[J].Environmental Chemistry Letters, 2022, 20:2339-2359.
[11] HAJDO L E, HALLAM R J, VORNDRAN L.Hydrogen generation during in-situ combustion[C].SPE California Regional Meeting,California:Society of Petroleum Engineers,1985,13661: 675-683.
[12] HALLAM R, HAJDO L, DONNELLY J, et al.Thermal recovery of bitumen at wolf lake[J]. SPE Reservoir Engineering, 1989, 4(2): 178-186.
[13] 油气计量及分析方法专业标准化技术委员会.SY/T 5402—2016原油含水量的测定电脱法[S].北京:石油工业出版社,2016:10.
Petroleum and Gas Measurement and Analysis Methods. SY/T 5402—2016Determination of water content in crude oil-Electric dehydration method [S].Beijing: Petroleum Industry Press,2016:10.
[14] ZHAO R, CHEN Y, HUAN R, et al.An experimental investigation of the in-situ combustion behavior of karamay crude oil[J]. Journal of Petroleum Science and Engineering, 2015, 127(1): 82-92.
[15] 姜丽娟.采气袋材质及存放时间对二氧化碳样品浓度的影响[J].环境与健康杂志,1999,16(1):39-40.
JIANG Lijuan.Effect of gas bag material and storage time on carbon dioxide sample concentration[J].Journal of Environment and Health,1999,16(1):39-40.
[16] 黄维民,刘燕,焦海峰,等.不同器材采集保存废气非甲烷总烃的准确性比较研究[J].环境与发展,2017,29(10):148-149.
HUANG Weimin,LIU Yan,JIAO Haifeng,et al.Comparative the accuracy of different equipment collection and save exhaust gas of NMHC[J].Environment and Development,2017,29(10):148-149.
[17] SHARMA K, DEEPU P, KUMAR S.Convective heat transfer in a tube filled with homogeneous and inhomogeneous porous medium[J].International Communications in Heat and Mass Transfer, 2020, 117: 104791.
[18] BELGRAVE J D M, MOORE R G, URSENBACH M G.Gas evolution from the aquathermolysis of heavy oils[J].Canadian Journal of Chemical Engineering, 1994, 72(3): 511-516.
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