注蒸汽开发后油藏火驱原位制氢可行性

doi:10.3969/j.issn.1006-6535.2024.01.010

特种油气藏 ›› 2024, Vol. 31 ›› Issue (1): 81-86.DOI: 10.3969/j.issn.1006-6535.2024.01.010

注蒸汽开发后油藏火驱原位制氢可行性

王田田¹, 赵仁保^1,2, 蒋宁宁¹, 李鑫¹, 徐晗¹, 王昊¹

1.中国石油大学(北京)油气资源与探测国家重点实验室,北京 102249;
2.中国石油大学(北京)克拉玛依校区,新疆克拉玛依 834000

收稿日期:2023-02-15 修回日期:2023-12-13 出版日期:2024-02-25 发布日期:2024-04-18
通讯作者: 赵仁保(1971—),男,教授,1994年毕业于河南大学化学专业,2006年毕业于中国石油大学(北京) 油气田开发专业,获博士学位,现主要从事稠油火驱理论及提高采收率工作。
作者简介:王田田(1995—),女,2014年毕业于延安大学化学专业,现为中国石油大学(北京)石油与天然气工程专业在读博士研究生,主要从事稠油原位制氢的实验研究工作。
基金资助:
国家自然科学基金“火线推进速度的预测和火腔在三维空间中演化的控制机制探索”(52274052);新疆维吾尔族自治区高层次人才引进项目“基于垂向火驱井网条件下超稠油的原位改质辅助开发机理研究”(JXDF0221)

Feasibility of In-Situ Hydrogen Production During Fire Flooding in Reservoirs after Steam Injection Development

Wang Tiantian¹, Zhao Renbao^1,2, Jiang Ningning¹, Li Xin¹, Xu Han¹, Wang Hao¹

1. State Key Laboratory of Oil and Gas Resources and Exploration of China University of Petroleum (Beijing), Beijing 102249, China;
2. China University of Petroleum-Beijing at Karamay, Karamay, Xinjiang 834000, China

Received:2023-02-15 Revised:2023-12-13 Online:2024-02-25 Published:2024-04-18

摘要/Abstract

摘要： 针对注蒸汽开发后油藏中火驱原位制氢技术的可行性问题,通过燃烧管实验,开展了含水饱和度对稠油原位制氢效果的影响研究。结果表明:水的存在增强了对流传热效应,为碳氢化合物中C—C和C—H的断裂提供了高温环境;并促进了稠油水热裂解、焦炭气化、水汽变换等可逆反应向制氢方向移动,提高了制氢效果。在含水饱和度为24.58%时,温度最高达715.1 ℃,氢气体积分数最高为1.03%。研究结果验证了注蒸汽开发后稠油油藏火驱原位制氢的可行性,该研究对提高稠油火驱原位制氢效果具有重要参考价值。

关键词: 稠油, 氢能, 火驱, 原位制氢, 含水饱和度

Abstract: A study on the influence of water saturation on the in-situ hydrogen production effect from heavy oil was carried out through combustion tube experiments to study the feasibility of technology on in-situ hydrogen production during fire flooding in reservoirs after steam injection development. The results show that the presence of water enhances the convective heat transfer effect and provides a high-temperature environment for the fracture of C-C and C-H in hydrocarbons and promotes the reversible reactions such as hydrothermal cracking, coke gasification, and water-steam conversion of heavy oil to move toward hydrogen production, which improves the in-situ hydrogen production effect. The temperature is 715.1 ℃, and the hydrogen volume fraction is up to 1.03% when the water saturation reaches 24.58%. The results verified the feasibility of in-situ hydrogen production from heavy oil during fire flooding in heavy oil reservoirs after steam injection development, and the study has significant reference value for improving the in-situ hydrogen production effect from heavy oil during fire flooding.

Key words: heavy oil, hydrogen energy, fire flooding, in-situ hydrogen production, water saturation

中图分类号:

TE357

王田田, 赵仁保, 蒋宁宁, 李鑫, 徐晗, 王昊. 注蒸汽开发后油藏火驱原位制氢可行性[J]. 特种油气藏, 2024, 31(1): 81-86.

Wang Tiantian, Zhao Renbao, Jiang Ningning, Li Xin, Xu Han, Wang Hao. Feasibility of In-Situ Hydrogen Production During Fire Flooding in Reservoirs after Steam Injection Development[J]. Special Oil & Gas Reservoirs, 2024, 31(1): 81-86.

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注蒸汽开发后油藏火驱原位制氢可行性

Feasibility of In-Situ Hydrogen Production During Fire Flooding in Reservoirs after Steam Injection Development

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