非常规储层纳米泡沫压裂液研究现状与展望

doi:10.3969/j.issn.1006-6535.2025.03.001

摘要/Abstract

摘要： 泡沫压裂液凭借低含水、易返排、携砂能力强、对储层伤害小等优点,成为非常规油气藏开发的关键技术之一。但泡沫的衰变问题严重影响了压裂的增产效果,随着纳米技术的发展,加入纳米颗粒提升泡沫压裂液的性能已成为研究热点。为此,介绍了纳米颗粒对泡沫压裂液稳定性、携砂性、降滤失性、伤害性的影响研究进展。并指明了下步研究方向,主要在利用机器学习算法和统计模型全面考虑各因素对泡沫稳定性的影响,加深纳米颗粒与表面活性剂的相互作用机制的认识,研发低成本高效纳米颗粒,降低纳米颗粒对储层的伤害,提高纳米泡沫压裂液在复杂储层环境下的稳定性和分散性等方面开展研究。研究成果可为纳米泡沫压裂液在非常规油气藏开发中的应用和发展提供理论参考和技术支持。

关键词: 压裂液, 非常规储层, 泡沫, 纳米颗粒

Abstract: Foam fracturing fluids, with benefits like low water content, easy flowback, strong sand-carrying capacity, and less reservoir damage, are a key technology for unconventional oil & gas reservoir development. However, foam decay greatly affects the stimulation by fracturing.With nano-technology progress, adding nanoparticles to boost foam fracturing fluid properties has become a research hotspot. This paper introduces the research progress of nanoparticle impacts on stability, sand-carrying capacity, fluid loss reduction, and damage reduction of foam fracturing fluids. It also points out future research directions, which mainly involve using machine learning algorithms and statistical models to holistically assess factors influencing foam stability, deepening the understanding of nanoparticle-surfactant interactions, developing low-cost and efficient nanoparticles, reducing nanoparticle-induced reservoir damage, and enhancing the stability and dispersion of nano-foam fracturing fluids in complex reservoir environments. The research findings can offer a theoretical reference and technical support for the application and development of nano-foam fracturing fluids in unconventional oil & gas reservoir exploitation.

Key words: fracturing fluid, unconventional reservoir, foam, nanoparticles

中图分类号:

TE357.1

姚伟达, 李宇, 张亮, 王鹏, 胡家晨, 马伟云, 支广超. 非常规储层纳米泡沫压裂液研究现状与展望[J]. 特种油气藏, 2025, 32(3): 1-7.

YAO Weida, LI Yu, ZHANG Liang, WANG Peng, HU Jiachen, MA Weiyun, ZHI Guangchao. Research status and prospects of nano-foam fracturing fluids in unconventional reservoirs[J]. Special Oil & Gas Reservoirs, 2025, 32(3): 1-7.

参考文献

[1] 姚艳斌,刘大锰.基于核磁共振弛豫谱技术的页岩储层物性与流体特征研究[J].煤炭学报,2018,43(1):181-189.
YAO Yanbin,LIU Dameng.Petrophysical properties and fluids transportation in gas shale:a NMR relaxation spectrum analysis method[J].Journal of China Coal Society,2018,43(1):181-189.
[2] 赵迪斐,张家明,郭英海,等.储层精细评价潜在关键关联指标:页岩沉积构造及其量化问题研究评述[J].非常规油气,2023,10(1):11-20.
ZHAO Difei,ZHANG Jiaming,GUO Yinghai,et al.Potential key correlation indicators for fine evaluation of reservoirs:review on shale sedimentary structure and its quantification[J].Unconventional Oil & Gas,2023,10(1):11-20.
[3] 张晴,任重阳,张然舜,等.基于文献计量特征的我国深层页岩研究进展及趋势(2012—2022)[J].非常规油气,2023,10(1):21-26.
ZHANG Qing,REN Zhongyang,ZHANG Ranshun,et al.Progress and trends of China′s deep shale gas research based on bibliometric analysis(2012-2022)[J].Unconventional Oil & Gas,2023,10(1):21-26.
[4] 陈江明.清洁二氧化碳泡沫压裂液稳定性研究[D].成都:西南石油大学,2016.
CHEN Jiangming.Study on stability of clean CO₂ foam fracturing fluid[D].Chengdu:Southwest Petroleum University,2016.
[5] 钱钦,鲁明晶,钟安海.东营凹陷陆相页岩油CO₂增能压裂裂缝形态研究[J].石油钻探技术,2023,51(5):42-48.
QIAN Qin,LU Mingjing,ZHONG Anhai.Study on fracture morphology of CO₂ energized fracturing of continental shale oil in Dongying Sag[J].Petroleum Drilling Techniques,2023,51(5):42-48.
[6] 申峰,杨洪,刘通义,等.抗高温清洁CO₂泡沫压裂液在页岩储层的应用[J].石油钻采工艺,2016,38(1):93-97.
SHEN Feng,YANG Hong,LIU Tongyi,et al.Application of high temperature clean CO₂ foam fracturing lfuid in shale gas reservoirs[J].Oil Drilling & Production Technology,2016,38(1):93-97.
[7] 郭建春,赵峰,詹立,等.四川盆地页岩气储层暂堵转向压裂技术进展及发展建议[J].石油钻探技术,2023,51(4):170-183.
GUO Jianchun,ZHAO Feng,ZHAN Li,et al.Recent advances and development suggestions of temporary plugging and diverting fracturing technology for shale gas reservoirs in the Sichuan Basin[J].Petroleum Drilling Techniques,2023,51(4):170-183.
[8] LI Songyan,YANG Kang,LI Zhaomin,et al.Properties of CO₂ foam stabilized by hydrophilic nanoparticles and nonionic surfactants[J].Energy & Fuels,2019,33(6):5043-5054.
[9] ALYOUSEF Z,ALOMBARKY M,SCHECHTER D S.The effect of nanoparticle aggregation on surfactant foam stability[J].Journal of Colloid and Interface Science,2018,511(9):365-373.
[10] BARUAH A,SHEKHAWAT D,PATHAK A,et al.Experimental investigation of rheological properties in zwitterionic-anionic mixed-surfactant based fracturing fluids[J].Journal of Petroleum Science and Engineering,2016,146:340-349.
[11] ZHU Jingyi,ZHENG Nanxin,YANG Zhaozhong,et al.Experimental study on the foam-stabilizing advantages and foam stabilization mechanism of novel microbial polysaccharides[J].Journal of Molecular Liquids,2023,385:122428.
[12] RAFATI R,HADDAD A,HAMIDI H.Experimental study on stability and rheological properties of aqueous foam in the presence of reservoir natural solid particles[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2016,509:19-31.
[13] CUI Z,CUI Y,CUI C,et al.Aqueous foams stabilized by in situ surface activation of CaCO₃ nanoparticles via adsorption of anionic surfactant[J].Langmuir,2010,26(15):12567-12574.
[14] PANAHPOORI D,REZVANI H,PARSAEI R.A pore-scale study on improving CTAB foam stability in heavy crude oil-water system using TiO₂ nanoparticles[J].Journal of Petroleum Science and Engineering,2019,183:106411.
[15] YEKEEN N,MANAN M,IDRIS A,et al.Mechanistic study of nanoparticles-surfactant foam flow in etched glass micro-models[J].Journal of Dispersion Science and Technology,2018,39(5):623-633.
[16] BAYAT A,RAJAEI K,JUNIN R.Assessing the effects of nanoparticle type and concentration on the stability of CO₂ foams and the performance in enhanced oil recovery[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2016,511:222-231.
[17] GONZENBACH U,STUDART A,TERVOORT E,et al.Stabilization of foams with inorganic colloidal particles[J].Langmuir,2006,22(26):10983-10988.
[18] YEKEEN N,PADMANABHAN E,IDRIS A K.Synergistic effects of nanoparticles and surfactants on n-decane-water interfacial tension and bulk foam stability at high temperature[J].Journal of Petroleum Science and Engineering,2019,179:814-830.
[19] MEHAIRI A,KHOSHNAZAR R,HUSEIN M.Stability of CO₂/N₂ foam generated in CaCO₃ nanoparticle/CTAB aqueous dispersion[J].Chemical Engineering Science,2024,286:119643.
[20] RAFATI R,HADDAD A,HAMIDI H.Experimental study on stability and rheological properties of aqueous foam in the presence of reservoir natural solid particles[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2016,509:19-31.
[21] 何宗礼,张雯,牛亮.双面神纳米颗粒的合成及其在稳泡方面的应用[J].当代化工,2021,50(12):2800-2824.
HE Zongli,ZHANG Wen,NIU Liang.Synthesis of janusnanoparticles and its applications in stabilizing bubbles[J].Contemporary Chemical Industry,2021,50(12):2800-2824.
[22] 张頔蕊.纳米二氧化钛与表面活性剂协同稳定泡沫及封堵性能[D].青岛:中国石油大学(华东),2020.
ZHANG Dirui.Study on synergistic stabilization of foam and plugging performance of nano - titanium dioxide and surfactant[D].Qingdao:China University of Petroleum(East China),2020.
[23] WORTHEN A,PARIKH P,CHEN Y,et al.Carbon dioxide-in-water foams stabilized with a mixture of nanoparticles and surfactant for CO₂ storage and utilization applications[J].Energy Procedia.2014,63:7929-7938.
[24] EMRANI A,NASR H.Stabilizing CO₂ foam by use of nanopraticles[C].SPE174254-MS,2017:494-504.
[25] ZHU Jingyi,YANG Zhaozhong,LI Xiaogang,et al.Experimental study on the microscopic characteristics of foams stabilized by viscoelastic surfactant and nanoparticles[J].Colloids and Surfaces A:Physicochemical and Engineering Aspect.2019,572:88-96.
[26] FEI Yang,ZHU Jingyi,XU Binyu,et al.Experimental investigation of nanotechnology on worm-like micelles for high-temperature foam stimulation[J].Journal of Industrial and Engineering Chemistry,2017,50:190-198.
[27] 王健,吴一慧,呙瑜成,等.纳米SiO₂强化阴/阳/非离子表面活性剂复配体系泡沫性能实验研究[J].精细与专用化学品,2018,26(1):33-37.
WANG Jian,WU Yihui,GUO Yucheng,et al.Experimental study on foam performance of nano-SiO₂ reinforced anionic/cationic/nonionic surfactant compounded system[J].Fine and Specialty Chemicals,2018,26(1):33-37.
[28] 李兆敏,张昀,李松岩,等.清洁泡沫压裂液研究应用现状及展望[J].特种油气藏,2014,21(5):1-6.
LI Zhaomin,ZHANG Yun,LI Songyan,et al.Current situation and prospect of research and application of clean foam fracturing fluid[J].Special Oil & Gas Reservoirs,2014,21(5):1-6.
[29] 彭欢,桑宇,杨建,等.泡沫压裂液携砂性能评价方法研究进展及展望[J].钻采工艺,2016,39(3):87-90.
PENG Huan,SANG Yu,YANG Jian,et al.Research and progress of evaluation method on foam fracturing fluid proppant carrying capability[J].Drilling & Production Technology,2016,39(3):87-90.
[30] VERMA A,CHAUHAN G,BARUAH P,et al.Morphology,rheology,and kinetics of nanosilica stabilized gelled foam fluid for hydraulic fracturing application[J].Industrial & Engineering Chemistry Research,2018,57(40):13449-13462.
[31] ZHU Jingyi,YANG Zhaozhong,LI Xiaogang,et al.Settling behavior of the proppants in viscoelastic foams on the bubble scale[J].Journal of Petroleum Science and Engineering,2019,181:106216.
[32] 杨兆中,郑南鑫,朱静怡,等.纳米颗粒强化泡沫压裂液的构建及其稳泡机理研究[J].油气藏评价与开发,2023,13(2):260-268.
YANG Zhaozhong,ZHENG Nanxin,ZHU Jingyi,et al.Preparation of nanoparticle-stabilized foam fracturing fluid and its foam stabilization mechanism[J].Reservoir Evaluation and Development,2023,13(2):260-268.
[33] FEI Y,JOHNSON R,GONZALEZ M,et al.Experimental and numerical investigation into nano-stabilized foams in low permeability reservoir hydraulic fracturing applications[J].Fuel,2018,213:133-143.
[34] 李川,张矿生,唐梅荣,等.一种高携砂性能的二氧化碳泡沫压裂液及其制备方法:202010149558.1[P].2020-03-06.
LI Chuan,ZHANG Kuangsheng,TANG Meirong,et al.A kind of CO₂ foam fracturing fluid with high sand-carrying capacity and its preparation method:202010149558.1[P].2020-03-06.
[35] 赵众从.缔合聚合物泡沫压裂液体系研究[D].成都:西南石油大学,2015.
ZHAO Zhongcong.Study on associated polymer foam fracturing fluid system[D].Chengdu:Southwest Petroleum University,2015.
[36] LYU Qichao,LI Zhaomin,LI Binfei,et al.Study of nanoparticle-surfactant-stabilized foam as a fracturing fluid[J].Industrial & Engineering Chemistry Research,2015,54(38):9468-9477.
[37] 张雨.基于温敏稳泡体系的微泡沫压裂液制备与稳定机理研究[D].青岛:中国石油大学(华东),2017.
ZHANG Yu.Research on preparation and stabilization mechanism of micro-foam fracturing fluid based on thermosensitive stabilization system[D].Qingdao:China University of Petroleum(East China),2017.
[38] FU Chunkai,LIU Ning.Waterless fluids in hydraulic fracturing-A review[J].Journal of Natural Gas Science and Engineering,2019,67:214-224.
[39] 吕其超,张星,周同科,等.SiO₂纳米颗粒强化的CO₂泡沫压裂液体系[J].中国石油大学学报(自然科学版),2020,44(3):114-123.
LYU Qichao,ZHANG Xing,ZHOU Tongke,et al.CO₂ foam fracturing fluid system enhanced by SiO₂ nanoparticles[J].Journal of China University of Petroleum(Edition of Natural Sciences),2020,44(3):114-123.
[40] TANG Quanwu,HUANG Zhiyu,WANG Baogang,et al.Surfactant-free aqueous foams stabilized with synergy of xanthan-based amphiphilic biopolymer and nanoparticle as potential hydraulic fracturing fluids[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2020,603:125215.
[41] 吕其超,李兆敏,李宾飞,等.纳米颗粒与黏弹性表面活性剂稳定的泡沫体系滤失性实验研究[J].中国科技论文,2017,12(3):241-248.
LYU Qichao,LI Zhaomin,LI Binfei,et al.Experimental study on filtration behavior of nanoparticles and viscoelastic surfactants stabilized foam[J].China Sciencepaper,2017,12(3):241-248.
[42] 吕其超.N₂/液态CO₂泡沫压裂液稳定、流变及滤失特性研究[D].青岛:中国石油大学(华东),2018.
LYU Qichao.Study on stability,rheology and filtration loss characteristics of N₂/liquid CO₂ foam fracturing fluid[D].Qingdao:China University of Petroleum(East China),2018.
[43] 刘帅.混合气体泡沫压裂液的研究[D].北京:中国石油大学(北京),2018.
LIU Shuai.Study on mixed gas foam fracturing fluid[D].Beijing:China University of Petroleum(Beijing),2018.
[44] IBRAHIM A,NASR-EL-DIN H.Stability improvement of carbon dioxide foam using nanoparticles and viscoelastic surfactants for enhanced-oil-recovery applications[C].SPE191251-PA,2020:414-430.
[45] MANSHA M,ALI S,ALSAKKAF M,et al.Advancements in nanoparticle-based stabilization of CO₂ foam:current trends,challenges,and future prospects[J].Journal of Molecular Liquids,2023,391:123364.
[46] DORDZIE G,DEJAM M.Enhanced oil recovery from fractured carbonate reservoirs using nanoparticles with low salinity water and surfactant:a review on experimental and simulation studies[J].Advances in Colloid and Interface Science,2021,293:102449.
[47] RAFATI R,HADDAD A,HAMIDI H.Experimental study on stability and rheological properties of aqueous foam in the presence of reservoir natural solid particles[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2016,509:19-31.
[48] LYU Qichao,ZHOU Tongke,LUAN Yingting,et al.A green aqueous foam stabilized by cellulose nanofibrils and camellia saponin for geological CO₂ sequestration[J].Journal of Cleaner Production,2023,406:136980.
[49] 白杨,王路一,李翔,等.煤层气储层保护钻井液技术研究进展[J].天然气工业,2024,44(10):182-194.
BAI Yang,WANG Luyi,LI Xiang,et al.Research progress of drilling fluid technology for CBM reservoir protection[J].Natural Gas Industry,2024,44(10):182-194.
[50] 辛骅志,杨万里,刘志强,等.砂砾岩储层多化学剂协同效应提高采收率机制研究[J].陕西科技大学学报,2022,40(5):108-116.
XIN Huazhi,YANG Wanli,LIU Zhiqiang,et al.Study on the mechanism of enhancing oil recovery by synergetic effect of multi chemical agents in glutenite reservoir[J].Journal of Shaanxi University of Science & Technology,2022,40(5):108-116.